Which spectral types correspond to the very hottest blue stars at the top of the temperature scale?

Answer

O and B types

The sequence of stellar classification types directly maps to the temperature gradient observed in star colors. At the highest temperature end of the scale are the blue stars, which are the hottest class. These correspond specifically to the O and B spectral types. These stellar objects burn at the highest surface temperatures recorded, contrasting sharply with cooler types. For instance, the hottest O-type blue stars can achieve surface temperatures exceeding 30,000 Kelvin, placing them firmly at the beginning of the O, B, A, F, G, K, M ordering, which is arranged by decreasing temperature.

Which spectral types correspond to the very hottest blue stars at the top of the temperature scale?
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