What event immediately forces the core of a star to begin contracting after the Main Sequence?
Answer
Exhaustion of hydrogen fuel in the star’s very center
The initiation of stellar expansion is directly tied to the termination of the primary energy source in the star's core. When the hydrogen fuel situated in the very center of the star is completely used up, the steady, outward pressure it generated suddenly ceases in that innermost region. Without this outward thermonuclear force to resist the star's own immense gravitational pull, the core is left unsupported, causing it to begin a rapid and powerful gravitational contraction under its own weight.

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