Why do the hottest stars (above 40,000 K) often lack core hydrogen fuel characteristic of main-sequence stars?

Answer

They are often post-main sequence, having evolved and shed outer hydrogen layers.

The very hottest stars observed are frequently post-main sequence; they have already burned through the hydrogen in their cores, evolved, and shed massive amounts of their outer hydrogen layers.

Why do the hottest stars (above 40,000 K) often lack core hydrogen fuel characteristic of main-sequence stars?
astronomytemperaturestarshottest