What material formed the heat shield for early crewed missions returning from the Moon, like the Apollo Command Module?

Answer

Phenolic epoxy resin

The Apollo Command Module heat shield relied on ablation using a high-density phenolic epoxy resin impregnated onto a honeycomb structure, which protected the craft through controlled material destruction.

What material formed the heat shield for early crewed missions returning from the Moon, like the Apollo Command Module?
AerospaceMaterialspacecraftreentryheat shield